| 谷氨酸柱撑水滑石超分子结构层柱材料的插层组装 |
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| 引用本文： | 任玲玲,何静,EVANS David G,段雪.谷氨酸柱撑水滑石超分子结构层柱材料的插层组装[J].高等学校化学学报,2003,24(1):169-173. |
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| 作者姓名： | 任玲玲 何静 EVANS David G 段雪 |
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| 作者单位： | 北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029 |
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| 基金项目： | 国家自然科学基金 (批准号 :2 99730 0 4)资助 |
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| 摘 要： | 用返混沉淀方法实现了谷氨酸柱撑水滑石超分子结构层柱材料的插层组装,得到结晶度高、晶相单一且谷氨酸在层间有序排列的超分子结构层柱材料.用X射线衍射、原子光谱、元素分析、红外光谱及热重-差热分析表征了超分子结构层柱材料的结构,给出其结构模型.
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| 关 键 词： | 谷氨酸 水滑石 超分子结构层柱材料 插层组装 |
| 文章编号： | 0251-0790(2003)01-0169-05 |
| 收稿时间： | 2001-11-28 |
Intercalation and Assembly of Supramolecular Materials of Glutamic Acid Pillared Layered Double Hydroxides |
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| EVANS David G.Intercalation and Assembly of Supramolecular Materials of Glutamic Acid Pillared Layered Double Hydroxides[J].Chemical Research In Chinese Universities,2003,24(1):169-173. |
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| Authors: | EVANS David G |
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| Institution: | Key Laboratory of Science &; Technology of Controllable Chemical Reactions, Education Ministry, Beijing University of Chemical Technology, Beijing 100029, China |
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| Abstract: | Glutamic acids were intercalated into the layered double hydroxides by a new synthesis method, from which high crystallized supramolecular materials were obtained and glutamate acids were ordered between layers without carbon dioxides. The structures of supramolecular materials were characterized by powder X-ray diffraction, atom absorbed spectra, FTIR spectra and thermal analysis and the structure models were given out. |
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| Keywords: | Glutamic acid Layered double hydroxides Supramolecular layered material Intercalation and assembly |
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