| 珠子参化学成分分析 |
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| 引用本文： | 时晓磊,王加付,姚华,张培旭,李绪文,张海玉,金永日.珠子参化学成分分析[J].高等学校化学学报,2013,34(2):381-385. |
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| 作者姓名： | 时晓磊 王加付 姚华 张培旭 李绪文 张海玉 金永日 |
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| 作者单位： | 1. 吉林大学军需科技学院, 长春 130062;
2. 吉林大学化学学院, 长春 130012;
3. 吉林大学第一医院, 长春 130021 |
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| 基金项目： | 国家自然科学基金(批准号:31201295)资助 |
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| 摘 要： | 从珠子参根茎中分离得到7个化合物. 利用核磁共振、 质谱和红外等手段, 并结合其理化性质, 鉴定了其结构, 它们分别是24(R)-珠子参苷R1, 6-O-β-D-吡喃葡萄糖基(1→2)-β-D-吡喃葡萄糖基]-20-O-β-D-吡喃葡萄糖基(1→4)-β-D-吡喃葡萄糖基]-20(S)-原人参三醇、 6″-乙酰基-人参皂苷Rd、 人参皂苷Rf、 竹节参皂苷Ⅳa、 人参皂苷Rd和竹节参皂苷Ⅴ. 其中, 24(R)-珠子参苷R1和6-O-β-D-吡喃葡萄糖基(1→2)-β-D-吡喃葡萄糖基]-20-O-β-D-吡喃葡萄糖基(1→4)-β-D-吡喃葡萄糖基]-20(S)-原人参三醇为2个新化合物, 6″-乙酰基-人参皂苷Rd 和人参皂苷Rf为首次从珠子参根茎中得到.
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| 关 键 词： | 珠子参 化学成分 皂苷 异核多重键相关谱 |
| 收稿时间： | 2012-06-20 |
Chemical Constituents of Roots of Panax japonicus C. A. Mey. var. major(Burk.)C. Y. Wu et K. M. Feng |
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| SHI Xiao-Lei,WANG Jia-Fu,YAO Hua,ZHANG Pei-Xu,LI Xu-Wen,ZHANG Hai-Yu,JIN Yong-Ri.Chemical Constituents of Roots of Panax japonicus C. A. Mey. var. major(Burk.)C. Y. Wu et K. M. Feng[J].Chemical Research In Chinese Universities,2013,34(2):381-385. |
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| Authors: | SHI Xiao-Lei WANG Jia-Fu YAO Hua ZHANG Pei-Xu LI Xu-Wen ZHANG Hai-Yu JIN Yong-Ri |
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| Institution: | 1. College of Quartermaster Technology, Jilin University, Changchun 130062, China;
2. College of Chemistry, Jilin University, Changchun 130012, China;
3. The First Hospital of Jilin University, Changchun 130021, China |
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| Abstract: | Seven compounds were isolated fromthe roots of Panax japonicus C. A. Mey. var. major(Burk.)C. Y. Wu et K. M. Feng. They were purified by chromatographic method. The structures of the compounds were deduced by spectroscopic methods as 24(R)-majoroside R1(1), 6-O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl]-20-O-β-D-glucopyranosyl-(1→4)-β-D-glucopyranosyl]-20(S)-protopanaxatriol(2), 6″-acetyl-ginsenoside-Rd(3), ginsenoside Rf(4), chikusetsusaponin-Ⅳa(5), ginsenoside Rd(6), Chikusetsusaponin-Ⅴ(7). Among them, 24(R)-majoroside R1 and-O-β-D-glucopyranosyl-(1→2)-β-D-glucopyranosyl]-20-O-β-D-glucopyranosyl-(1→4)-β-D-glucopyranosyl]-20(S)-protopanaxatriol are new compounds; 6″-acetyl-ginsenoside-Rd and ginsenoside Rf are isolated from Panax japonicus C. A. Mey. var. major(Burk.)C. Y. Wu et K. M. Feng for the first time. |
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| Keywords: | Panax japonicus C A Panax japonicus C" target="_blank">Mey')" href="#">Panax japonicus C A Mey Chemical constituent Saponin Heteronuclear multiple bonding correlation |
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