| 丙烯酸甲酯-三烯丙基氰尿酸酯和二乙烯苯共聚物MA/TD的合成及其孔结构的研究(Ⅲ) |
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| 引用本文： | 何炳林,张耕宜,郭贤权,赵芬芝,杨志欣.丙烯酸甲酯-三烯丙基氰尿酸酯和二乙烯苯共聚物MA/TD的合成及其孔结构的研究(Ⅲ)[J].高等学校化学学报,1989,10(2):182. |
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| 作者姓名： | 何炳林 张耕宜 郭贤权 赵芬芝 杨志欣 |
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| 作者单位： | 南开大学高分子化学研究所 |
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| 摘 要： | 制备了一系列丙烯酸甲酯(MA)-三烯丙基氰尿酸酯(TAC)和二乙烯苯(DVB)混合交联剂的共聚物小球,测定和讨论了混合交联剂、致孔剂用量和性质等诸因素对共聚物的比表面积、孔容、平均孔径,孔径分布和孔度的影响。同时,初步探讨活性相对较低的三烯丙基氰尿酸酯在混合交联共聚中的作用。
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| 关 键 词： | 丙烯酸甲酯 三烯丙基氰尿酸酯 二乙烯苯 |
| 收稿时间： | 1987-07-18 |
Investigation of Preparation of Copolymer of Triallyl Cyanurate DVB and Methyl Acrylate and Their Pore Structure |
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| He Binglin,Zhang Gengyi,Guo Xianquan,Zhao Fenzhi,Yang Zhixin.Investigation of Preparation of Copolymer of Triallyl Cyanurate DVB and Methyl Acrylate and Their Pore Structure[J].Chemical Research In Chinese Universities,1989,10(2):182. |
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| Authors: | He Binglin Zhang Gengyi Guo Xianquan Zhao Fenzhi Yang Zhixin |
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| Institution: | Institute of Macromolecular Chemistry, Nankai University, Tianjin |
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| Abstract: | A series of copolymers were prepared by methyl acrylate and triallyl cyanurate and divinylbenzene. The effects of properties and amounts of mixed cross linking agent and diluents on physical properties, such as specific surface area, pore volume, average pore diameter, pore size distribution and porosity were investigated and disscused. The affect of the lower activities of triallyl cyanurate in a mixed cross linking agent copolymerization were disscused. |
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| Keywords: | Methyl acrylate Triallyl cyanurate Divinylbenzene |
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