| 用ICP-AES研究负载奎宁/活性炭新吸附材料对钨酸根阴离子的吸附行为 |
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| 引用本文： | 刘怀志,姜轶婉,胡斌,廖振环,江祖成.用ICP-AES研究负载奎宁/活性炭新吸附材料对钨酸根阴离子的吸附行为[J].高等学校化学学报,1997,18(11):1788. |
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| 作者姓名： | 刘怀志 姜轶婉 胡斌 廖振环 江祖成 |
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| 作者单位： | 武汉大学化学系, 武汉 430072 |
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| 摘 要： | 柱分离／预富集与原子光谱检测技术联用在痕量分析和形态分析中发挥着日益重要的作用，钨分离富集用的固定相在文献中已有一些报道，如活性炭'、阴离子交换树脂'、流基棉Dj以及高分子螫合吸附剂D－'等．基于生物碱类试剂在一定条件下可以与某些金属阴离于或者杂多酸根阴离子形成稳定的、组成确定的配合物的特性，本工作采用浸渍法将生物碱试剂奎宁负载在活性炭上，制得一种新的金属阴离子吸附材料--负载奎宁／活性炭．采厅ICP－AES检测手段对该吸附材料在静态吸附条件下对金属阴离子WOS吸附性能进行了详细考察；研究了影响待测物…
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| 关 键 词： | 奎宁 活性炭 吸附材料 钨酸根 ICP－AES |
| 收稿时间： | 1996-08-10 |
Using ICP-AES to Investigate Adsorption Behavior of Quinine-Loaded Active Carbon on Metallic Anion WO_4~(2-) |
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| LIU Huai-Zhi, JIANG Yi-Wan, HU Bin, LIAO Zhen-Huan, JIANG Zu-Cheng.Using ICP-AES to Investigate Adsorption Behavior of Quinine-Loaded Active Carbon on Metallic Anion WO_4~(2-)[J].Chemical Research In Chinese Universities,1997,18(11):1788. |
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| Authors: | LIU Huai-Zhi JIANG Yi-Wan HU Bin LIAO Zhen-Huan JIANG Zu-Cheng |
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| Institution: | Department of Chemistry, Wuhan University, Wuhan 430072 |
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| Abstract: | Anew metallic anion adsorbent quinine-loaded active carbon was prepared.ICP AESwas used to study its adsorptive property for metallic anion WO42-.The chemicalstability of the adsorbent was investigated.The effects of different concentrations of HCl andNH3· H2Osolution on adsorption rate and desorption rate as well as the interference effectsof some other ions were studied respectively.The method has been applied to thedetermination of trace tungsten in standard reference sample GSD-11. |
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| Keywords: | Quinine Active carbon Adsorbent Tungstate radical ICP-AES |
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