| Cl-对API P105钢在含CO2溶液中的电化学腐蚀行为的影响 |
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| 引用本文： | 张学元,余刚,王凤平,杜元龙.Cl-对API P105钢在含CO2溶液中的电化学腐蚀行为的影响[J].高等学校化学学报,1999,20(7):1115-1118. |
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| 作者姓名： | 张学元 余刚 王凤平 杜元龙 |
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| 作者单位： | 金属腐蚀与防护国家重点实验室,中国科学院金属腐蚀与防护研究所,沈阳,110015 |
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| 基金项目： | 中国科学院九五重大项目,国家自然科学基金 |
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| 摘 要： | 用电化学阻抗谱（ＥＩＳ）及极化测量，研究了在含ＣＯ２的溶液中Ｃｌ＾－１对ＡＰＩＰ１０５钢的电化学腐蚀行为的影响。结果表明，Ｃｌ＾－促进了钢铁的阳极溶解，其电化学反应级数为０．７．Ｃｌ＾－不参与钢铁的阴极反应，在含Ｃｌ＾－的饱和ＣＯ２溶液中，阴极反应主要为Ｈ２ＣＯ３的去极化反应。
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| 关 键 词： | 腐蚀机理 API P105钢 |
Influence of Cl- on Corrosion Behavior of API P105 Steel in the CO2 Saturated Solution |
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| ZHANG Xue-Yuan,YU Gang,WANG Feng-Ping,DU Yuan-Long.Influence of Cl- on Corrosion Behavior of API P105 Steel in the CO2 Saturated Solution[J].Chemical Research In Chinese Universities,1999,20(7):1115-1118. |
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| Authors: | ZHANG Xue-Yuan YU Gang WANG Feng-Ping DU Yuan-Long |
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| Abstract: | Corrosion mechanism for API P105 steel in the CO 2 saturated solution with Cl - was studied by using electrochemical impedance spectroscopy(EIS) and polarization measurements. The results showed that Cl - promoted the dissolution of iron, and the order of the electrochemical reaction was 0 7, Cl - did not take part in the cathodic reaction, the main cathodic reaction was controlled by the depolarization reaction of H 2CO 3. |
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| Keywords: | Cl- CO2 |
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