| 液相一步合成金红石型超细TiO2 |
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| 引用本文： | 赵敬哲,王子忱,刘艳华,王莉玮,宋庆,杨桦,赵慕愚,冯守华,徐如人.液相一步合成金红石型超细TiO2[J].高等学校化学学报,1999,20(3):467-469. |
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| 作者姓名： | 赵敬哲 王子忱 刘艳华 王莉玮 宋庆 杨桦 赵慕愚 冯守华 徐如人 |
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| 作者单位： | 1. 吉林大学化学系,长春,130023
2. 吉林大学无机水热合成开放实验室,长春,130023 |
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| 基金项目： | 吉林省科学技术发展规划资助,吉林大学无机水热合成开放实验室资助 |
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| 摘 要： | 二氧化钛在自然界中存在三种结晶形态：金红石型、锐钛矿型和板钛矿型．金红石型ＴｉＯ２因其折射率高，性能优越，因而得到广泛的应用［１～３］．传统金红石型ＴｉＯ２的制备需经高温固相反应，经历由无定形→锐钛矿→金红石的转化过程．通常情况下，锐钛矿到金红石型Ｔ...
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| 关 键 词： | 金红石型 二氧化钛 胶溶 |
Preparation of Ultrafine Rutile Titania Crystals by Liquid Method |
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| ZHAO Jing-Zhe,WANG Zi-Chen,LIU Yan-Hua,WANG Li-Wei,SONG Qing,YANG Hua,ZHAO Mu-Yu,FENG Shou-Hua,XU Ru-Ren.Preparation of Ultrafine Rutile Titania Crystals by Liquid Method[J].Chemical Research In Chinese Universities,1999,20(3):467-469. |
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| Authors: | ZHAO Jing-Zhe WANG Zi-Chen LIU Yan-Hua WANG Li-Wei SONG Qing YANG Hua ZHAO Mu-Yu FENG Shou-Hua XU Ru-Ren |
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| Abstract: | Rutile titania crystals were directly prepared in liquid system without anatase\|to\|rutile transformation, while Ti(SO\-4)\-2 and ammonia are the raw materials. The process of preparation can be divided into two parts: one is precipitating, the other is peptizing. The conditions of \{precipitating\} influence the structure of the resulted crystals, even though \{Ti(OH)\-4\} precipitates \{obtained\} during precipitating are amorphous. Peptizing is the process of the formation of crystals, the amorphous Ti(OH)\-4 precipitates changing into titania with the change of rutile structure. |
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| Keywords: | Rutile Titania Peptizing |
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