| 三维无机-有机杂化骨架微孔材料Cd(HBTC)(EG)·8(H2O)的合成与结构 |
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| 引用本文： | 方千荣,朱广山,石鑫,辛明红,吴刚,田歌,叶玲,王春雷,张震东,裘式纶.三维无机-有机杂化骨架微孔材料Cd(HBTC)(EG)·8(H2O)的合成与结构[J].高等学校化学学报,2003,24(5):776-778. |
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| 作者姓名： | 方千荣 朱广山 石鑫 辛明红 吴刚 田歌 叶玲 王春雷 张震东 裘式纶 |
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| 作者单位： | 吉林大学化学学院,无机合成与制备化学国家重点实验室,长春130023 |
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| 基金项目： | 国家自然科学基金(批准号:29873017,20101004)，国家重大基础研究计划“973”项目(批准号:G2000077507) |
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| 摘 要： | 由于无机-有机杂化微孔晶体材料在选择性催化、分子识别和可逆性主客体分子(离子)交换等方面存在潜在的应用前景,已经越来越引起人们的广泛注意.传统的沸石和分子筛微孔晶体材料以硅酸盐、硅铝酸盐、磷铝酸盐和无机金属磷酸盐为骨架,新型的无机-有机杂化微孔晶体材料用刚性和热稳定性较好的有机分子和金属离子作为结构单元.均苯三甲酸(H3BTC)是常用的含氧有机配.
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| 关 键 词： | 无机-有机杂化骨架结构 晶体结构 微孔材料 |
| 文章编号： | 0251-0790(2003)05-0776-03 |
| 收稿时间： | 2002-12-18 |
| 修稿时间： | 2002年12月18 |
Synthesis and Characteristic of a 3-D Inorganic-organic Hybrid Framework Microporous Material Cd(HBTC)(EG)·8(H2O) |
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| FANG Qian-Rong,ZHU Guang-Shan,SHI Xin,XIN Ming-Hong,WU Gang,TIAN Ge,YE Ling,WANG Chun-Lei,ZHANG Zhen-Dong,QIU Shi-Lun.Synthesis and Characteristic of a 3-D Inorganic-organic Hybrid Framework Microporous Material Cd(HBTC)(EG)·8(H2O)[J].Chemical Research In Chinese Universities,2003,24(5):776-778. |
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| Authors: | FANG Qian-Rong ZHU Guang-Shan SHI Xin XIN Ming-Hong WU Gang TIAN Ge YE Ling WANG Chun-Lei ZHANG Zhen-Dong QIU Shi-Lun |
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| Institution: | College of Chemistry, State Key laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China |
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| Abstract: | The title compound Cd(HBTC)(EG)·8(H2O) was synthesized under mild conditions and its crystal structure was determined by means of single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The compound crystallizes in the monoclinic system and belongs to space group P21/n with a=0. 7311(15) nm, b=1. 8306(4) nm, c=0.9500(19) nm, β= 109. 69(3)% V=1. 1970(4) nm3, Z=4, Dc= 4. 832 g/cm3, Mr= 526. 72, μ= 2. 981 mm-1, F(000)=1716, GOF=1. 146, R=0. 0958, Rw= 0. 2762. Its structure revealed that coordination of HBTC ligands with Cd ions forms a 2-D network along be plane, while 4,4'-bpy as pillars uphold the 2-D network to lead to a 3-D framework along a axis. |
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| Keywords: | Inorganic-organic hybrid framework 5 Crystal structure Microporous material |
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