| “哑铃状”偶氮化合物的合成与表征 |
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| 引用本文： | 毛华平,于有海,陈梁,卢晓峰,张万金,张红星.“哑铃状”偶氮化合物的合成与表征[J].高等学校化学学报,2006,27(10):1999-2001. |
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| 作者姓名： | 毛华平 于有海 陈梁 卢晓峰 张万金 张红星 |
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| 作者单位： | 1. 吉林大学麦克德尔米德实验室,长春,130012
2. 吉林大学理论化学计算国家重点实验室,长春,130021 |
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| 基金项目： | 国家重点基础研究发展计划(973计划);重大国际合作项目;国家自然科学基金 |
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| 摘 要： | 从分子设计的角度出发, 合成了末端含有两个庞大基团的哑铃状偶氮化合物. 其大的末端基团一方面可以增加顺、反两种异构体之间的能垒, 有利于两种异构体的稳定存在, 另一方面由于大的末端基团的存在, 为采用AFM或高分辨STM直接观测两种异构体分子相的相互转变降低了难度.
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| 关 键 词： | 偶氮 哑铃 紫外 顺反异构 理论计算 |
| 文章编号： | 0251-0790（2006）10-1999-03 |
| 收稿时间： | 03 7 2006 12:00AM |
| 修稿时间： | 2006-03-07 |
Synthesis and Characterization of a Novel Azo Compound with 'Dumbbell Shape' |
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| MAO Hua-Ping,YU You-Hai,CHEN Liang,LU Xiao-Feng,ZHANG Wan-Jin,ZHANG Hong-Xing.Synthesis and Characterization of a Novel Azo Compound with ''''Dumbbell Shape''''[J].Chemical Research In Chinese Universities,2006,27(10):1999-2001. |
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| Authors: | MAO Hua-Ping YU You-Hai CHEN Liang LU Xiao-Feng ZHANG Wan-Jin ZHANG Hong-Xing |
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| Institution: | 1. Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China; 2. Institute of Theoretical Chemistry, State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130021, China |
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| Abstract: | A novel azo compound with 'dumbbell shape' was synthesized successfully and characterized by MALDI-MS,FTIR,elemental analysis,1H NMR and 13C NMR.UV-Vis spectrum was used to monitor the trans-cis isomerization and theoretical calculations were used to modelize the trans and cis isomers.The trans and cis isomers of the 'dumbbell shape' azo compound are both stable at room temperature because of the large end group. |
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| Keywords: | Azobenzene Dumbbell UV-Vis spectrum cis-trans isomerization Theoretical calculation |
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