| C60与甲基丙烯酸甲酯共聚物的制备及光电导性能的研究 |
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| 引用本文： | 汪长春,陶征洪,胡建华,府寿宽.C60与甲基丙烯酸甲酯共聚物的制备及光电导性能的研究[J].高等学校化学学报,2000,21(5):805-808. |
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| 作者姓名： | 汪长春 陶征洪 胡建华 府寿宽 |
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| 作者单位： | 复旦大学高分子科学系, 教育部聚合物分子工程开放实验室, 上海 200433 |
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| 基金项目： | 国家自然科学基金青年基金!（批准号：59703004） |
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| 摘 要： | 通过自由基聚合的方法制备了一系列甲基丙烯酸甲酯和C60的共聚物,实验结果表明,增加引发剂的含量可以大大提高共聚物的产率。用元素分析、GPC和DSC等方法对共聚物进行表征。首次尝试研究了不含导电高分子的C60共聚物体系的光电导性能,结果表明,该类共聚物光电导性能良好。
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| 关 键 词： | 甲基丙烯酸甲酯和C60的共聚物 C60 光电导材料 |
| 收稿时间： | 1999-03-30 |
Preparation and Photoconductivity Study of the C60/MMA Copolymers |
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| WANG Chang-Chun,TAO Zheng-Hong,HU Jian-Hua,FU Shou-Kuan.Preparation and Photoconductivity Study of the C60/MMA Copolymers[J].Chemical Research In Chinese Universities,2000,21(5):805-808. |
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| Authors: | WANG Chang-Chun TAO Zheng-Hong HU Jian-Hua FU Shou-Kuan |
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| Institution: | Department of Macromolecular Science, the Key Laboratory of Polymer Molecular Engineering of Educational Ministry, Fudan University, Shanghai 200433, China |
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| Abstract: | A series of C60/MMA copolymers were synthesized by free radical polymerization. The experimental results showed that the polymerization conversion rate went up along with Increasing the amount of initiator dramatically. Meanwhile, the C60/MMA copolymers were characterized by the techniques of elemental analysis, GPC and DSC. In this paper, the photoconductivity of the C60/MMA copolymers was al- so studied, and the influence parameters, such as exposure intensity, thickness of interface layer, of the photoconductivity have been discussed, separately. From the experimental results, it can be conclude that C60/MMA copolymers will become a candidate of photoelectric materials. |
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| Keywords: | C_(60)/MMA copolymers C_(60) Photoelectric materials |
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