| 含能配位聚合物[ Cu(tza)2]n的晶体结构、热分析、感度和催化性能 |
| |
| 引用本文： | 汤崭,张国涛,张同来,李志敏,杨利,张建国,乔小晶.含能配位聚合物[ Cu(tza)2]n的晶体结构、热分析、感度和催化性能[J].高等学校化学学报,2011,32(8):1870-1875. |
| |
| 作者姓名： | 汤崭 张国涛 张同来 李志敏 杨利 张建国 乔小晶 |
| |
| 作者单位： | 北京理工大学爆炸科学与技术国家重点实验室,北京,100081 |
| |
| 基金项目： | 爆炸科学与技术国家重点实验室自主探索基金(批准号:YBKT10-05); 重点资助基金(批准号:ZDKT10-01b)资助 |
| |
| 摘 要： | 以碱式碳酸铜和四氮唑乙酸在水中反应制备得到四唑乙酸铜(Ⅱ)含能配位聚合物Cu(tza)2]n,并培养出单晶.运用元素分析、FHIR分析和X射线单晶衍射对含能配位聚合物的组成和结构进行了表征,采用差示扫描量热分析( DSC)和热重,微分热重分析(TG-DTG)研究了含能配位聚合物的热分解过程,结果表明,Cu(tza)...
|
| 关 键 词： | 含能配位聚合物 四氮唑乙酸 晶体结构 热分析 催化性能 |
Crystal Structure,Thermal Properties,Sensitivity Test and Catalytic Activity of Energetic Compound[Cu(tza)_2]_n |
| |
| TANG Zhan,ZHANG Guo-Tao,ZHANG Tong-Lai,LI Zhi-Min,YANG Li,ZHANG Jian-Guo,QIAO Xiao-Jing.Crystal Structure,Thermal Properties,Sensitivity Test and Catalytic Activity of Energetic Compound[Cu(tza)_2]_n[J].Chemical Research In Chinese Universities,2011,32(8):1870-1875. |
| |
| Authors: | TANG Zhan ZHANG Guo-Tao ZHANG Tong-Lai LI Zhi-Min YANG Li ZHANG Jian-Guo QIAO Xiao-Jing |
| |
| Institution: | TANG Zhan,ZHANG Guo-Tao,ZHANG Tong-Lai,LI Zhi-Min,YANG Li,ZHANG Jian-Guo,QIAO Xiao-Jing (State Key Laboratory of Explosion Science and Technology,Beijing Institute of Techonoly,Beijing 100081,China) |
| |
| Abstract: | Copper based on tetrazole-1-acetate acid Cu(tza)2]n was synthesized with tetrazole-1-acetate acid(Htza) and cupric carbonate basic in aqueous solution,and its single crystal was obtained.The molecular formula and structure of Cu(tza)2]n was characterized by the elemental analysis and FTIR techniques,and the result is in accordance with the X-ray single crystal diffraction data.The thermal decomposition process of Cu(tza)2]n was investigated by differential scanning calorimetry(DSC) and thermogravimetry-d... |
| |
| Keywords: | Energetic coordination compound Tetrazole-1-acetic acid Crystal structure Thermal analysis Catalytic property |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
