| 四(对-癸酰氧基)苯基卟啉过渡金属配合物的合成及红外光声光谱解析 |
| |
| 引用本文： | 柳巍,师同顺,安庆大,杨大智.四(对-癸酰氧基)苯基卟啉过渡金属配合物的合成及红外光声光谱解析[J].高等学校化学学报,2001,22(1):16-20. |
| |
| 作者姓名： | 柳巍 师同顺 安庆大 杨大智 |
| |
| 作者单位： | 1. 第四军医大学, 吉林大学化学系, 长春130032;
2. 大连理工大学化学系, 大连116024 |
| |
| 基金项目： | 国家自然科学基金(批准号：59783001)资助. |
| |
| 摘 要： | 合成出相变温度较低、相区宽的卟啉液晶5,10,15,20-四(对-癸酰氧基)苯基卟啉简称TDPPH2]及其Mn(Ⅲ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ)配合物.通过元素分析、紫外可见光谱、红外光声光谱、核磁共振氢谱和摩尔电导等分析方法表征了它们的组成和结构,并用DSC和偏光显微镜研究了配体及其锌配合物的液晶行为.测试并研究了配体及其配合物在3600～190cm-1范围内的傅里叶变换红外光声光谱,对其主要谱带进行了经验归属.
|
| 关 键 词： | 四(对-癸酰氧基)苯基卟啉 配合物 卟啉液晶 红外光声光谱 |
| 文章编号： | 0251-0790(2001)01-0016-05 |
| 收稿时间： | 1999-12-06 |
Synthesis of Tetra(4-n-decanoyloxyphenyl)porphyrin Complexes and Fourier Transform Infrared Photoacoustic Spectra |
| |
| LIU Wei,SHI Tong-shun,AN Qing-Da,YANG Da-zhi.Synthesis of Tetra(4-n-decanoyloxyphenyl)porphyrin Complexes and Fourier Transform Infrared Photoacoustic Spectra[J].Chemical Research In Chinese Universities,2001,22(1):16-20. |
| |
| Authors: | LIU Wei SHI Tong-shun AN Qing-Da YANG Da-zhi |
| |
| Institution: | 1. Department of Chemistry, Jilin University, Changchun 130023, China;
2. Department of Chemistry, Dalian University of Science and Technology, Dalian 116024, China |
| |
| Abstract: | Six complexes of tetra (4-n-octanoyloxyphenyl)porphyins with Mn(Ⅲ),Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ) and Zn(Ⅱ) have been synthesized in mixed solvents CH2Cl2＋DMF.The complexes were determined by elemental analysis,UV-Vis,FTIR photoacoustic spectrum,1H NMR and molar conductivity measurement.The domains of stability and the structure of the liquid crystalline phases are determined by optical microscopy and differential scanning calorimerials (DSC).The fourier transform infrared photoacoustic spectra of TDPPH2 and its complexes in the range of 3 600－190 cm-1 were measured and investigated. |
| |
| Keywords: | Tetra(4 n octanoyloxyphenyl)porphyrin Complex Porphyrin liquid crystal Infrared photoacoustic spectra |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
