| γ-苄基膦酸-磷酸锆的合成、表征及插层性能研究 |
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| 引用本文： | 黄坤林,于吉红,邹永存,李彩今,王光美,丁红,荆维杰,徐如人.γ-苄基膦酸-磷酸锆的合成、表征及插层性能研究[J].高等学校化学学报,2004,25(8):1387-1390. |
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| 作者姓名： | 黄坤林 于吉红 邹永存 李彩今 王光美 丁红 荆维杰 徐如人 |
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| 作者单位： | 吉林大学化学学院,无机合成与制备化学国家重点实验室,长春,130023 |
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| 基金项目： | 国家自然科学基金 (批准号 :G2 0 0 0 0 775 0 7)资助 |
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| 摘 要： | 于220℃水热晶化下制备了高结晶度的γ-ZrP,合成了3种γ-苄基膦酸-磷酸锆层状化合物Zr(PO4).(H2PO4)0.15(C6H5CH2PO3H)0.85·0.4H2O(1,d=1.86nm),Zr(PO4)(H2PO4)0.30(C6H5CH2PO3H)0.70·0.6H2O(2,d=1.78nm)和Zr(PO4)(H2PO4)0.50(C6H5CH2PO3H)0.50·0.7H2O(3,d=1.66nm).用X射线粉末衍射和31P固态核磁共振等手段表征其结构,并研究了其与α-苯乙胺的插层性能.
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| 关 键 词： | γ-磷酸锆 苄基膦酸 γ-苄基膦酸-磷酸锆 31P固态核磁共振 插层组装 |
| 文章编号： | 0251-0790(2004)08-1387-04 |
| 收稿时间： | 2003-12-23 |
Synthesis, Characterization and Intercalation Behavior of γ-Zirconium Benzylphosphonate-phosphates |
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| HUANG Kun-Lin,YU Ji-Hong ,ZOU Yong-Cun,LI Cai-Jin,WANG Guang-Mei,DING Hong,JIN Wei-Jie,XU Ru-Ren.Synthesis, Characterization and Intercalation Behavior of γ-Zirconium Benzylphosphonate-phosphates[J].Chemical Research In Chinese Universities,2004,25(8):1387-1390. |
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| Authors: | HUANG Kun-Lin YU Ji-Hong ZOU Yong-Cun LI Cai-Jin WANG Guang-Mei DING Hong JIN Wei-Jie XU Ru-Ren |
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| Institution: | HUANG Kun-Lin,YU Ji-Hong *,ZOU Yong-Cun,LI Cai-Jin,WANG Guang-Mei,DING Hong,JIN Wei-Jie,XU Ru-Ren |
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| Abstract: | γ-ZrP with a high crystallinity was prepared at 220 ℃. Three γ -zirconium benzylphosphonate-phosphates,formulated as Zr(PO4)(H2PO4)0.15 (C6H5CH2PO3H)0.85 ·0.4H2O(1, d=1.86 nm), Zr(PO4) (H2PO4)0.30 (C6H5CH2PO3H)0.70 ·0.6H2O(2, d=1.78 nm) and Zr(PO4)(H2PO4)0.50 ·(C6H5CH2PO3H)0.50 ·0.7H2O(3, d=1.66 nm),were synthesized and characterized by means of 31P MAS NMR,XRD and TG method. The intercalation behavior of the new compounds with α -phenylethylamines are investigated. |
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| Keywords: | γ-ZrP Benzylphosphonic acid γ-Zirconium benzylphosphonate-phosphates 31P MAS NMR" target="_blank">31P MAS NMR')" href="#">31P MAS NMR Intercalation |
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