| 季铵盐单体在蒙脱土中的插层原位聚合反应 |
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| 引用本文： | 冯莉,杨穆,王戈.季铵盐单体在蒙脱土中的插层原位聚合反应[J].高等学校化学学报,2006,27(11):2213-2216. |
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| 作者姓名： | 冯莉 杨穆 王戈 |
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| 作者单位： | 1. 北京化工大学理学院,北京,100029
2. 北京科技大学材料科学与工程学院,北京,100083 |
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| 基金项目： | 国家自然科学基金;北京科技大学校科研和教改项目 |
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| 摘 要： | 通过四种结构相似的可聚合季铵盐(二甲基二烯丙基氯化铵、三甲基烯丙基氯化铵、丙烯酰氧乙基三甲基氯化铵、甲基丙烯酰氧乙基三甲基氯化铵), 通过蒙脱土层间构型排布的模拟及分析比较, 从分子水平上探讨了原位插层聚合反应中, 单体分子排列角度及构型对聚合反应的影响.
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| 关 键 词： | 蒙脱土 原位插层聚合 季铵盐单体 |
| 文章编号： | 0251-0790（2006）11-2213-04 |
| 收稿时间： | 02 24 2006 12:00AM |
| 修稿时间： | 2006-02-24 |
In situ Polymerization of Ammonium Ion Monomers Intercalated in the Montmorillonite Template |
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| FENG Li,YANG Mu,WANG Ge.In situ Polymerization of Ammonium Ion Monomers Intercalated in the Montmorillonite Template[J].Chemical Research In Chinese Universities,2006,27(11):2213-2216. |
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| Authors: | FENG Li YANG Mu WANG Ge |
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| Institution: | 1. School of Science, Beijing University of Chemical Technology, Beijing 100029, China ; School of Material Science and Engineering, Beijing University of Science and Technology, Beijing 100083, China |
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| Abstract: | The protonated forms of four ammonium salts(dimethyl diallyl ammonium chloride,DMDAAC;trimethylallyl ammonium chloride,TMAAC;acryloxyethyl trimethylammonium chloride,DAC;2-methyl acryloxyethyltrimethylammonium chloride,DMC) were introduced into the interlayer region of montmorillonite template through ion-exchange reaction.X-ray diffractometry and FTIR spectra displayed that all the four monomers were intercalated into the layer region successfully,but only two monomers undertook in situ polymerization.The different reaction activities of the four monomers were attributed to the different space arrangement and steric hindrance of the monomers in the interlayer of montmonrillonite template. |
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| Keywords: | Montmorillonite In situ intercalation polymerization Ammonium ion monomer |
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