| 取代型钨镓杂多配合物的导电性及其磁性 |
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| 引用本文： | 王力,刘宗瑞.取代型钨镓杂多配合物的导电性及其磁性[J].高等学校化学学报,1997,18(6):846-850. |
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| 作者姓名： | 王力 刘宗瑞 |
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| 作者单位： | 内蒙古民族师范学院函授部(王力，刘宗瑞)，东北师范大学化学系!长春，130024(周云山，王恩波) |
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| 基金项目： | 国家自然科学基金，吉林大学无机水热合成重点实验室基金，南京大学配位化学国家重点实验室基金 |
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| 摘 要： | 合成了过渡金属取代的钨镓杂多配合物α－Ｎａ７「ＧａＷ１１Ｃｏ（Ｈ２Ｏ）Ｏ３９」．１６Ｈ２Ｏ，α－Ｎａ７Ｈ２「ＧａＷ１０Ｃｏ２（Ｈ２Ｏ）２Ｏ３９」．１６Ｈ２Ｏ和α－ＮａｎＨｍ「ＧａＷ９ＭＥ（Ｈ２Ｏ）３Ｏ３７」．１６Ｈ２Ｏ「Ｍ＝Ｃｏ（Ⅱ），Ｎｉ（Ⅱ，）Ｖ（Ⅴ）」，通过红外，紫外，ＩＣＰ，ＴＧ－ＤＴＡ，ＥＰＲ，ＸＰＳ，＾１８３ＷＮＭＲ，极谱等手段进行了表征。
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| 关 键 词： | 钨镓杂多配合物 磁性 电导率 取代型 |
Studies on the Conductivity and Magnetic Properties of Substituted Heteropoly Tungstogallates |
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| WANG Li, LIU Zong-Rui, ZHOU Yun-Shan, WANG En-Bo.Studies on the Conductivity and Magnetic Properties of Substituted Heteropoly Tungstogallates[J].Chemical Research In Chinese Universities,1997,18(6):846-850. |
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| Authors: | WANG Li LIU Zong-Rui ZHOU Yun-Shan WANG En-Bo |
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| Abstract: | Five substituted tungstogallate complexes were synthesized and characterized by IR, UV, ICP, TG-DTA, 183W NMR, EPR, XPS. The determination of conductivity ex-hibits that the complexes are an excellent high-proton conductor. In which, d value of GaW9Co3 is above 10-3 S. cm-1 at room temperature and 10-2 S. cm-1 at 343 K. The mag-netic susceptibility data obtained in the range of 75-300 K have been fitted with J and g,based on the spin Hamiltonian H |
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| Keywords: | Tungstogallate heteropoly complex Magnetic properties Conductivity |
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