| 铁,钴,铜酞菁／Y型分子筛的制备,表征及催化苯酚羟化的研究 |
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| 引用本文： | 齐兴义,张伟德.铁,钴,铜酞菁／Y型分子筛的制备,表征及催化苯酚羟化的研究[J].高等学校化学学报,1995,16(5):791-795. |
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| 作者姓名： | 齐兴义 张伟德 |
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| 作者单位： | 吉林大学化学系，中国科学院长春应用化研究所 |
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| 摘 要： | 制备了铁，钴，铜酞菁／Ｙ型发子筛，利用元素分析，ＩＲ、ＵＶ－Ｖｉｓ，ＴＧ、ＢＥＴ及ＸＲＤ确定了分子筛笼中铁，钴，铜酞菁化合物的生成及其晶体结构，考察了实验参数对苯酚的转化率及产物选择性的影响。
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| 关 键 词： | 酞菁 Y型分子筛 苯酚羟化 铁 钴 铜 |
Studies on Preparation of Iron ,Cobalt and CopperPhthalocyanines/Y Zeolite , Characterization andTheir Catalysis for Hydroxylation of Phenol |
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| QI Xing-Yi, WANG Guo-Jia.Studies on Preparation of Iron ,Cobalt and CopperPhthalocyanines/Y Zeolite , Characterization andTheir Catalysis for Hydroxylation of Phenol[J].Chemical Research In Chinese Universities,1995,16(5):791-795. |
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| Authors: | QI Xing-Yi WANG Guo-Jia |
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| Abstract: | Iron, cobalt and copper phthalocyanines/Y zeolite, denoted as FepcY,CopcY and CupcY respectively ,were prepared. The formation of metal phthalocyanine compounds with in the cages of Y zeolite and their crystal structures were determined by elementary analyses ,IR ,UV-Vis,TG , BET, and XRD methods ; The influence of experimental parameters upon phenol conversion and product selectivities was investigated as well. |
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| Keywords: | Metal phthalocyanine Zeolite Phenol hydroxylation |
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