| 四(对-辛酰氧基)苯基卟啉配合物的红外光声光谱 |
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| 引用本文： | 师同顺,柳巍,王银杰,赵军,刘国发.四(对-辛酰氧基)苯基卟啉配合物的红外光声光谱[J].高等学校化学学报,1998,19(11):1794-1798. |
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| 作者姓名： | 师同顺 柳巍 王银杰 赵军 刘国发 |
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| 作者单位： | 吉林大学化学系, 长春, 130023 |
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| 基金项目： | 国家自然科学基金,吉林省科委基金 |
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| 摘 要： | 测试并研究了四(对-辛酰氧基)苯基卟啉及其Mn(Ⅲ)、Fe(Ⅲ)、co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)配合物在3600～190cm-1范围内的傅立叶变换红外光声光谱,对主要谱带进行了经验归属.结果表明:3318.0和968.0cm-1处的吸收谱带分别是四(对-辛酰氧基)苯基卟啉N-H键的伸缩振动和面内弯曲振动,生成配合物后这些谱带消失.～243cm-1处的吸收谱带是M-N键伸缩振动和卟啉环变形振动的复合振动,～320cm-1处的吸收谱带是M-Cl键的伸缩振动,金属敏感带出现在1504,1350,1022,995,796和235cm-1处.
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| 关 键 词： | 四(对-辛酰氧基)苯基卟啉 配合物 红外光声光谱 卟啉 含长碳链的卟啉 |
| 收稿时间： | 1997-09-27 |
Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(para-octanoyloxyphenyl)Porphyrin Complexes |
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| SHI Tong-Shun,LIU Wei,WANG Yin-Jie,ZHAO Jun,LIU Guo-Fa.Fourier Transform Infrared Photoacoustic Spectroscopy of Tetra(para-octanoyloxyphenyl)Porphyrin Complexes[J].Chemical Research In Chinese Universities,1998,19(11):1794-1798. |
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| Authors: | SHI Tong-Shun LIU Wei WANG Yin-Jie ZHAO Jun LIU Guo-Fa |
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| Institution: | Department of Chemistry, Jilin University, Changchun, 130023 |
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| Abstract: | The fourier transform infrared photoacoustic spectra of tetra-(para octanoyloxyphenyl) porphyrin T(p-OO)PPH2 and its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) complexes in the range of 3600～190 cm-1 were measured and investigated. The bands at 3318.0 and 968.0 cm-1 of T(p-OO)PPH2 are due to the N-Hstretching and in plane and out-plane bending vibration of the pyrrole groups. All these bands disappear upon complexes formation. The vibration coupling between the M-N stretching and the porphyrin ring deformation appears at 243 cm-1. Metal sensitive bands were found at 1504, 1350, 1022, 995, 796 and 235 cm-1. |
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| Keywords: | Tetra ( para octanoyloxyphenyl) porphyrin Complex Infrared photoacoustic spectrum Porphyrin Porphyrin derivatives with long carbon chain |
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