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富勒烯烟炱的吸附性及其在大气挥发性有机物分析中的应用
引用本文:陈建新,陈才,盛国英,王新明,傅家谟,刘子阳,刘淑莹.富勒烯烟炱的吸附性及其在大气挥发性有机物分析中的应用[J].高等学校化学学报,2000,21(1):45-48.
作者姓名:陈建新  陈才  盛国英  王新明  傅家谟  刘子阳  刘淑莹
作者单位:1. 中国科学院广州地球化学研究所有机地球化学国家重点实验室, 广州 510640; 2. 中国科学院长春应用化学研究所, 长春 130022
基金项目:国家自然科学基金! (批准号 :4 96 32 0 6 0及 4 96 752 71)资助
摘    要:研究了富勒烯烟炱对挥发性有机物(VOCs)的吸附作用.17种VOCs气体在烟炱上的比保留体积Vg20为17.4~2634L/g.富勒烯烟炱充填的吸附管对VOCs气体的吸附-热脱附回收率在40.8%~117%之间,大部分为(100±20)%.结果表明,富勒烯烟炱能够用于吸收和富集大气中痕量的VOCs

关 键 词:挥发性有机物(VOCs)  吸附剂  富勒烯烟炱  
收稿时间:1999-05-05

Adsorption Characteristics of Fullerene-extracted Soots and Its Application for Collecting Volatile Organic Compounds in Ambient Air
CHEN Jian-Xin,CHEN Cai,SHENG Guo-Ying,WANG Xin-Ming,FU Jia-Mo,LIU Zi-Yang,LIU Shu-Ying.Adsorption Characteristics of Fullerene-extracted Soots and Its Application for Collecting Volatile Organic Compounds in Ambient Air[J].Chemical Research In Chinese Universities,2000,21(1):45-48.
Authors:CHEN Jian-Xin  CHEN Cai  SHENG Guo-Ying  WANG Xin-Ming  FU Jia-Mo  LIU Zi-Yang  LIU Shu-Ying
Institution:1. State Key Laboratory of Organic Geochemistry, Gruangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China; 2. Changchun Instituteof App lied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Abstract:Fullerene-extracted soots which are the by-product of producing fullerenes(C60/C70) can adsorb organic vapors efficiently. Breakthrough volumes(maximum sample volumes, Vmax)and specific retention volumes(20 ℃)of 17 VOCs(volatile organic compounds)are measured. The recoveries of adsorption/thermal desorption of Fullerene-extracted soots adsorbent tubes ranged from 40.8% to 117%, most of which are (100±20)%. Fullerene-extracted soots is cheap and can be used in environmental analysis for trapping and enriching traces of VOCs in ambient air.
Keywords:Volatile organic compounds(VOCs)  Adsorbent  Fullerene-extracted soots  
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