Über Blei (II)-oxidhydrat der Zusammensetzung 3PbO·H2O

Lead oxide hydrate mentioned in the earlier literature with several formulas between PbO · H₂O and PbO · 0.33 H₂O has been synthesized and investigated by high resolution X-ray powder methods, thermogravimetry and infrared spectroscopy. The unit cell was found from 62 powder reflections to be tetragonal with a = 8.009 ± 0.003 Å, c = 9.312 ± 0.005 Å, Z = 12 PbO · 0.33 H₂O]. These data were confirmed by WEISSENBERG and Precession photographs of single crystals grown as a corrosion product on metallic lead. The space group is D–P4/mnc or C–P4 nc. Thermogravimetric measurements, corrected for a slight content of superficially bound carbon dioxide detected by infrared spectroscopy, lead to the most probable formula 3 PbO · H₂O or PbO · 0.33 H₂O. As infrared spectra show the presence of a HOH deformation vibration, the compound is considered to be an oxide hydrate and not an oxide hydroxide of lead.