Solid-state luminescence of Au(I) complexes with external stimuli-responsive properties |
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Institution: | 1. Division of Applied Chemistry and Frontier Chemistry Center (FCC), Faculty of Engineering, Hokkaido University, Sapporo, Hokkaido, 060-8628, Japan;2. Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Hokkaido University, Sapporo, Hokkaido, 060-8628, Japan |
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Abstract: | In the last decade, the field of stimuli-responsive luminescent materials have been intensely emerged because of the high potential application to functional sensors or photoelectronic devices. In particular, luminescent molecular crystals constructed from Au(I) complexes have produced a wide range of examples of luminescent alterations when some external stimulations, such as heat, mechanical stress, vapor (or solvents), were applied to the solid samples. In this review, we describe the recent progress through a summary of the reported Au(I) complexes based on their utilized stimuli-responsive mechanisms, which are categorized in crystal phase transitions (“crystal-to-amorphous”, “crystal-to-crystal” and “single-crystal-to-single-crystal” transitions) and molecular rotation in crystalline media, respectively. |
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Keywords: | Luminescent Au(I) complexes External-stimuli-responsive solid-state emission Crystalline phase transition Crystalline molecular rotors |
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