| Abstract: | Five new peltogynoids, irisoids A-E (1-5), have been isolated from the underground parts of Iris bungei. The structures of the new compounds were established on the basis of spectroscopic methods and were found to be 1,8,10-trihydroxy-9-methoxy-1]benzopyrano-3,2-c]2]-benzopyran-7(5H)-one (1), 1,8-dihydroxy-9,10-dimethoxy-1]benzopyrano-3,2-c]2]-benzopyran-7(5H)-one (2), 1,10-dihydroxy-8,9-dimethoxy-1]benzopyrano-13,2-c]2]-benzopyran-7(5H)-one (3), 1,8-dihydroxy-9,10-methylenedioxy-1]benzopyrano-3,2-c]2]-benzopyran-7(5H)-one (4), and 1,8,11-trihydroxy-9,10-methylenedioxy-1]benzopyrano-3,2-c]2]-benzopyran-7(5H)-one (5). The structure of irisoid B (2) was established unambiguously by X-ray diffraction study. |
