Synthesis of 1-hetarylethylphosphonates |
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Authors: | N S Gulyukina I P Beletskaya |
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Institution: | 1.Faculty of Chemistry,Moscow State University,Moscow,Russia |
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Abstract: | Previously unknown potentially biologically active diethyl 1-(pyridin-3-yl)-, 1-(quinolin-3-yl)-, and 1-(quinolin-6-yl)ethylphosphonates
were synthesized by palladium-catalyzed reduction of the corresponding α,β-unsaturated precursors with ammonium formate. The
reduction of diethyl 1-(quinolin-6-yl)ethenylphosphonate was accompanied by formation of diethyl 1-(1,2,3,4-tetrahydroquinolin-6-yl)ethylphosphonate
as by-product. |
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