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Application of a Carbon‐Paste Electrode Modified with 2,7‐Bis(ferrocenyl ethyl)fluoren‐9‐one and Carbon Nanotubes for Voltammetric Determination of Levodopa in the Presence of Uric Acid and Folic Acid
Authors:Hadi Beitollahi  Jahan‐Bakhsh Raoof  Rahman Hosseinzadeh
Institution:1. Environmet Department, Research Institute of Environmental Sciences, International Center for Science, High Technology & Environmental Sciences, Kerman, Iran phone: 00983426226613;2. fax: 00983426226617;3. Electroanalytical Chemistry Research Laboratory, Department of Analytical Chemistry, Faculty of Chemistry,University of Mazandaran, Babolsar, Iran;4. Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran
Abstract:A carbon‐paste electrode modified with 2,7‐bis(ferrocenyl ethyl)fluoren‐9‐one and carbon nanotubes was used for the sensitive voltammetric determination of levodopa (LD). The electrochemical response characteristics of the modified electrode toward LD, uric acid (UA) and folic acid (FA) were investigated. The results showed an efficient catalytic activity of the electrode for the electrooxidation of LD, which leads to lowering its overpotential by more than 320 mV. The modified electrode exhibits an efficient electron mediating behavior together with well‐separated oxidation peaks for LD, UA and FA. Also, the modified electrode was used for determination of LD in some real samples.
Keywords:Levodopa  Uric acid  Folic acid  Carbon nanotubes  Modified electrode  Electrocatalysis
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