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Hierarchical Porous Tubular Biochar Based Sensor for Detection of Trace Lead (II)
Authors:Xue Chen  Kunchao Lu  Donghai Lin  Yan Li  Shiyu Yin  Zhiyi Zhang  Meihua Tang  Guosong Chen
Institution:1. College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009 China;2. School of Environmental and Materials Engineering, College of Engineering, Shanghai Polytechnic University, Shanghai, 201209 China;3. College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, 210009 China
Abstract:Hierarchical porous tubular biochar (PTBC) was prepared by selectively removing lignin simply according to reverse the pyrolysis sequence of cellulose. The properties of the PTBC sample were characterized by XRD, SEM, TEM, Raman spectra, cyclic voltammetry and electrochemical impedance spectroscopy. The electrochemical performances of PTBC modified on the screen-printing electrode illustrated excellent detection of lead ions (lead (II)) in water with the linear range (0.5–120 μg/L) and the detection limit (0.02 μg/L) by in-situ bismuth film square wave anode stripping voltammetry.
Keywords:Biochar  Fiber frame structure  Lead ions  Electrochemical sensor  Screen-printing electrode
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