A 2‐fold Interpenetrated Framework based on Tetranuclear Heterometallic Cluster: Synthesis,Structure and Magnetic Properties |
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| Authors: | Guang‐Xiang Liu Prof Dr Heng Xu Xiao‐Ming Ren |
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| Institution: | Anqing / P. R. China, Provincial Key Laboratory of Functional Coordination Chemistry, College of Chemistry and Chemical Engineering, Anqing Normal University |
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| Abstract: | A 2‐fold parallel interpenetrated polymer, ZnCo(OH)(pheno)(p‐BDC)1.5·H2O ( 1 ) (pheno = phenanthrene‐9,10‐dione; p‐BDC = 1,4‐benzenedicarboxylate) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, ICP and single crystal X‐ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three‐dimensional (3D) six‐connected α‐Po network. The magnetic behavior for 1 was studied in the temperature range of 1.8‐300 K. |
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| Keywords: | Carboxylate ligand Heterometallic complex α ‐Po Magnetic Property |
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