Nitrosyl Rhenium Complexes Syntheses,Properties, and Structures of Oxalato Derivatives |
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| Authors: | T Mitra A Bhadra S Sen B K Sen P Bandyopadhyay |
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| Abstract: | The free acid, HRe(NO)(C2O4)(OH)2(H2O)] has been prepared from the reaction of Re(NO)(OH)3 ? H2O with oxalic acid in aqueous medium. The K+, NH4+ and Pb2+ salts of the acid have been isolated. Nonelectrolytic diimino derivatives, Re(NO)(C2O4)X · L (X = 1, 10-phenanthroline, 2,2′-dipyridyl; L ? OH?, Cl?) have been synthesized. The complexes have been characterised through elemental analyses, spectral (u.v., vis., i.r.) properties, magnetic and conductance data and their structures are proposed. |
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