|
|||||
|
|
The Crystal and Molecular Structure of γ‐P4S6 |
|
| Authors: | Thomas Rödl Prof Dr Arno Pfitzner |
| Institution: | Institut für Anorganische Chemie Universit?t Regensburg Universit?tsstra?e 31 93040 Regensburg, Germany |
| Abstract: | The crystal and molecular structure of γ‐P4S6 was determined from single‐crystal X‐ray diffraction. It crystallizes monoclinically in the space group P21/m (No. 11) with a = 6.627(3) Å, b = 10.504(7) Å, c = 6.878(3) Å, β = 90.18(4)°, V = 478.8(4) Å3, and Z = 2. The structure consists of cage‐like P4S6 molecules with CS symmetry arranged with the topology of a cubic close packing. |
| Keywords: | Phosphorus Sulfur Phosphorus sulfides Cage molecules |