{[Mn2(μ3‐Tda)2(μ‐H2O)(H2O)2(bipy)]·DMF}n – a 2D Manganese(II) Coordination Polymer involving Six‐membered Binuclear Metallacycle Nodes |
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| Authors: | Ya‐Qian Cheng Hong‐Ping Xiao Xin‐Hua Li Jia‐Guo Wang Ali Morsali Dr |
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| Institution: | 1. Wenzhou/China, School of Chemistry and Materials Science, Wenzhou University;2. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O.Box 14155‐4838, Tehran /I. R. IranDepartment of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O.Box 14155‐4838, Tehran /I. R. Iran |
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| Abstract: | The single crystal X‐ray analysis of a novel thiophene‐2,5‐dicarboxylic acid (H2Tda) Manganese(II) coordination polymer, {Mn2(μ3‐Tda)2(μ‐H2O)(H2O)2(bipy)]·DMF}n, shows two different types of Mn2+‐ions with environment of Mn1O6 and Mn2O4N2, and the complex is a two‐dimensional polymer as a result of bridging (Tda)2? ligands and by connecting the carboxylate‐ and water‐bridged {Mn2(μ‐Tda)2(μ‐H2O)} nodes. |
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| Keywords: | Manganese Coordination polymers Thiophene‐2 5‐dicarboxylic acid 2 2′ ‐Bipyridine |
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