Über verschiedene Reaktionen der CO-verbrückten Komplexe [Mo(CO)3bipy]2 und [Mo(CO)3phen]2 (bipy = 2,2′-Bipyridyl,phen = 1,10-Phenanthrolin) |
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Authors: | H Behrens G Lehnert H Sauerborn |
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Abstract: | The interaction of Mo(CO)3bipy]2 with various monodentate ligands L (L = NH3, pyr, P(C6H5)3, P(C6H5)Cl2, CN?, SO2) yields, according to the reaction equation in ?Inhaltsübersicht”?, mixed tricarbonyl compounds Mo(CO)3bipyL by cleavage of the CO bridges of the dimeric starting carbonyl. Oxidation of Mo(CO)3D]2 (D = bipy, phen) by means of iodine, partly in the presence of free bipy or phen, leads to the covalent and ionic, respectively, compound types MoII(CO)3DI2]2, MoI(CO)2DI]2, MoII(CO)2D2I]I and MoII(CO)2D2I]I3. |
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