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新型耐腐蚀含氟环氧乙烯基酯树脂的合成与性能
引用本文:仇伟,潘沛颐,李晓艳,李欣欣,韩哲文.新型耐腐蚀含氟环氧乙烯基酯树脂的合成与性能[J].功能高分子学报,2011,24(3):256-261.
作者姓名:仇伟  潘沛颐  李晓艳  李欣欣  韩哲文
作者单位:华东理工大学材料科学与工程学院,特种功能高分子材料及相关技术教育部重点实验室,上海200237
基金项目:上海市重点学科资助项目(B502)
摘    要:以含氟环氧树脂(F-EP)、丙烯酸(AA)和甲基丙烯酸(MAA)为单体,用顺丁烯二酸(MA)进行改性,合成了含氟环氧乙烯基酯树脂(F-EVER)。用傅里叶红外光谱、热重分析、力学性能分析等手段对产物进行表征,研究了树脂的耐腐蚀性能。结果表明:当以N,N-二甲基甲酰胺(DMF)为催化剂,羧基与环氧基摩尔比为0.9,MA与...

关 键 词:含氟聚合物  乙烯基酯树脂  耐腐蚀性能

Synthesis and Performance of Novel Fluorine-Containing Epoxy Vinyl Ester Resin
QIU Wei,PAN Pei-yi,LI Xiao-yan,LI Xin-xin,HAN Zhe-wen.Synthesis and Performance of Novel Fluorine-Containing Epoxy Vinyl Ester Resin[J].Journal of Functional Polymers,2011,24(3):256-261.
Authors:QIU Wei  PAN Pei-yi  LI Xiao-yan  LI Xin-xin  HAN Zhe-wen
Institution:QIU Wei,PAN Pei-yi,LI Xiao-yan,LI Xin-xin,HAN Zhe-wen(Key Laboratory for Specially Functional Polymers and Related Technology of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China)
Abstract:A novel fluorine-containing epoxy vinyl ester resin(F-EVER) was synthesized using fluorine-containing epoxy(F-EP),acrylic acid(AA) and methacrylic acid(MAA) as monomer.The resin was modified by maleic acid(MA),FT-IR spectra,TGA and mechanical properties.The corrosive resistance of the cured resin was also investigated.Results showed that the F-EVER had best performance when resin was synthesized under DMF as catalyst,molar ratio of carboxyl groups to epoxy groups was 0.9,molar ratio of F-EP to MA was more t...
Keywords:fluorine-containing polymer  epoxy vinyl ester resin  corrosion resistant property  
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