| 脱氢枞胺键合交联聚苯乙烯树脂的制备 |
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| 引用本文： | 何曼,沈德渊.脱氢枞胺键合交联聚苯乙烯树脂的制备[J].功能高分子学报,2001,14(3):268-274. |
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| 作者姓名： | 何曼 沈德渊 |
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| 作者单位： | 1. 东南大学化学化工系,
2. 南京林业大学理化中心, |
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| 摘 要： | 运用高分子反应法，制备脱氢枞胺键合交联聚苯乙烯树脂，反应分三步进行：醚化反应，双键环氧化和脱氢枞胺与环氧基开环反应，探讨了每一步合成的最佳工艺条件，通过红外光谱对该功能高分子进行了结构表征，并对该合成产物进行对映体分离的初步应用。
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| 关 键 词： | 脱氢枞胺 交联聚苯乙烯树脂 手性固定相 醚化 环氧化 液相色谱 制备 |
| 文章编号： | 1008-9357(2001)03-0268-07 |
| 修稿时间： | 2001年4月2日 |
Preparation and Characterization of Covalently Bonded Dehydroabietylamine Derivatized Cross-linked Polystyrene |
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| HE Man,SHEN De yuan.Preparation and Characterization of Covalently Bonded Dehydroabietylamine Derivatized Cross-linked Polystyrene[J].Journal of Functional Polymers,2001,14(3):268-274. |
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| Authors: | HE Man SHEN De yuan |
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| Abstract: | To produce covalently bonded dehydroabietylamine derivatized cross linked polystyrene by macromolecular reaction. The synthetic method involves three steps. The first step is synthesis of ethers and the second step is epoxidation of double bonds. The third step is reaction of dehydroabietylamine with epoxy group. The optimum technological conditions of each step were discussed. The functional macromolecular were characterized by IR. And the product was tried to resolute enantiomers. |
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| Keywords: | dehydroabietylamine cross linked polystyrene chiral stationary phase synthesis of ethers epoxidation |
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