| 含氟丙烯酸酯共聚乳液的制备及表征 |
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| 引用本文： | 赵兴顺,丁小斌,郑朝晖,潘毅,朱珠,戴静,彭宇行.含氟丙烯酸酯共聚乳液的制备及表征[J].功能高分子学报,2003,16(4):436-440. |
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| 作者姓名： | 赵兴顺 丁小斌 郑朝晖 潘毅 朱珠 戴静 彭宇行 |
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| 作者单位： | 中国科学院成都有机化学研究所,四川,成都,610041 |
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| 摘 要： | 采用十二烷基硫酸钠和壬基酚聚氧乙烯醚(OP-10)混合乳化剂，制备了粒径为40-50nm的甲基丙烯酸全氟辛基乙酯(FMA8)-甲基丙烯酸丁酯(BMA)-甲基丙烯酸(MA)共聚物乳液。通过DSC、、FTIR、^1H-NMR等手段对共聚物进行了表征。考察了乳液的稳定性、乳胶膜的吸水性和耐溶剂性以及全氟单体的含量对聚合反应的影响。
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| 关 键 词： | 含氟丙烯酸酯共聚乳液 制备 结构表征 稳定性 吸水性 耐溶剂性 聚合反应 全氟单体含量 |
| 文章编号： | 1008-9357(2003)04-0436-05 |
| 修稿时间： | 2003年7月3日 |
Preparation and Characterization of Fluorine-Containing Copolymer Emulsion |
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| ZHAO Xing-shun,DING Xiao-bin,ZHENG Zhao-hui,PAN Yi,ZHU Zhu,DAI Jing,PENG Yu-xing.Preparation and Characterization of Fluorine-Containing Copolymer Emulsion[J].Journal of Functional Polymers,2003,16(4):436-440. |
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| Authors: | ZHAO Xing-shun DING Xiao-bin ZHENG Zhao-hui PAN Yi ZHU Zhu DAI Jing PENG Yu-xing |
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| Abstract: | Stable copolymer latex with range of 40-50 nm were prepared by emulsion polymerization of fluorinated monomer FMA8 with BMA and MAA using SDS and OP-10 as emulsifier. Hie copolymer was characterized by DSC.FT-IR and 'H-NMR. The water absorption ability of latex films was decreased with increasing the content FMA8 content of copolymer. The effect of concentration of FMA8 on emulsion polymerization was studied. |
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| Keywords: | perfluoroalkylethyl methacrylate emulsion copolymerization fluorine acrylate |
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