| 原子转移自由基聚合制备聚酯二元醇接枝聚苯乙烯 |
| |
| 引用本文： | 黄昌国,万小龙,胡志强,应圣康.原子转移自由基聚合制备聚酯二元醇接枝聚苯乙烯[J].功能高分子学报,2000,13(2):169-172. |
| |
| 作者姓名： | 黄昌国 万小龙 胡志强 应圣康 |
| |
| 作者单位： | 华东理工大学材料科学研究所,上海,200237 |
| |
| 基金项目： | 国家自然科学基金!项目 (2 96 340 10 .2 ) |
| |
| 摘 要： | 聚酯二元醇经氯甲基化制备了聚酯二元醇大分子引发剂，通过原子转移自由基聚合技术，合成了聚酯二元醇－ｇ－聚苯乙烯接枝聚合物。用＾１Ｈ－ＮＭＲ、ＦＴ－ＩＲ和ＧＰＣ表征了接枝聚合物，结果表明分子量与转化率呈线性关系，且分子量分布较窄，接枝聚合反应是一个可控过程。
|
| 关 键 词： | 接枝共聚物 聚酯多元醇 苯乙烯 ATRP |
Sythesis of Polyester Polyol-g-Polystyrene by Atom Transfer Radical Polymerization |
| |
| HUANG Chang-guo,WAN Xiao-long,HU Zhi-qiang,YING Sheng-kang.Sythesis of Polyester Polyol-g-Polystyrene by Atom Transfer Radical Polymerization[J].Journal of Functional Polymers,2000,13(2):169-172. |
| |
| Authors: | HUANG Chang-guo WAN Xiao-long HU Zhi-qiang YING Sheng-kang |
| |
| Abstract: | Chloromethylated polyester polyol, the macroinitiator for atom transfer radical polymerization (ATRP), was prepared by chloromethlating the aromatic rings of polyester's backbone. Polyester polyol-g-polystyrene was synthesized by CuCl-catalyzed ATRP of styrene (St). The linear relationship between the number average molecular weight vs monomer conversion and the narrow molecular weight dispersion indicated that the polymerization was a well-controlled process. The graft copolymers were confirmed by gel permeation chromatograph (GPC), 1 H-NMR and FT-IR. |
| |
| Keywords: | graft copolymer atom transfer radical polymerization polyester polyol styrene |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
