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氨基改性聚醚型聚硅氧烷的制备及其柔软性能研究
引用本文:安秋凤,李临生,陈孔常.氨基改性聚醚型聚硅氧烷的制备及其柔软性能研究[J].功能高分子学报,2001,14(4):399-404.
作者姓名:安秋凤  李临生  陈孔常
作者单位:1. 华东理工大学化学与制药学院,上海 210037;西北轻工业学院,咸阳 712081
2. 西北轻工业学院,咸阳 712081
3. 华东理工大学化学与制药学院,上海 210037
摘    要:用含氢硅油、烯丙基缩水甘油醚、烯基聚醚的硅氢化加成产物-聚醚/环氧硅油与胺反应制得了氨基改性聚醚型聚硅氧烷(APEPS),对其结构与性能进行了表征和研究。结果表明,含氢硅油分子量、有机胺结构、氨基改性聚醚型聚硅氧烷的硅含量对APEPS性能有影响。提高硅含量、增加氨值,可改善APEPS的柔软性与滑爽感,但对织物的吸湿性影响不大。

关 键 词:氨基改性聚醚型聚硅氧烷  织物柔软剂  制备  整理剂  柔软性能
文章编号:1008-9357(2001)04-0399-06
修稿时间:2001年7月10日

Preparation of Amino Modified Polyether Polysiloxanes and thei r Softness on Fabrics
AN Qiu feng ,LI Lin sheng ,CHEN Kong chang.Preparation of Amino Modified Polyether Polysiloxanes and thei r Softness on Fabrics[J].Journal of Functional Polymers,2001,14(4):399-404.
Authors:AN Qiu feng  LI Lin sheng  CHEN Kong chang
Institution:AN Qiu feng 1,LI Lin sheng 2,CHEN Kong chang 1
Abstract:Amino modified polyether polysiloxanes (APEPS) were prepared by the reaction of amines with polyether /epoxy functional silicone, which is formed from hydrosilylation of methyl hydrogen silicone with allyl gylcidyl ether and polyoxyalkylene containing vinyl group. The structure and properties of APEPS was studied and characterized. The results showed that the average molecular weight of methyl hydrogen silicone, amine structure and Si content in amino modified polyether polysiloxanes have some effects on APEPS performance. By increasing Si content and amino equivalent of APEPS, the softness and smoothness of finished fabrics is improved, but fabric rewettability is little changed.
Keywords:amino modified polyether polysiloxane  polyether  /epoxy functional silicone  fabric softener
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