Oxidative rearrangement of tertiary allylic alcohols employing oxoammonium salts |
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| Authors: | Shibuya Masatoshi Tomizawa Masaki Iwabuchi Yoshiharu |
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| Institution: | Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama, Sendai, Japan. |
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| Abstract: | Practical and highly efficient methods for oxidative rearrangement of tertiary allylic alcohols to beta-substituted alpha,beta-unsaturated carbonyl compounds employing oxoammonium salts are described. The methods developed are applicable to acyclic substrates as well as medium membered ring substrates and macrocyclic substrates. The counteranion of the oxoammonium salt plays crucial roles on this oxidative rearrangement. |
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