Halide-free dehydrative allylation using allylic alcohols promoted by a palladium-triphenyl phosphite catalyst |
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| Authors: | Kayaki Yoshihito Koda Takashi Ikariya Takao |
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| Institution: | PRESTO, Japan Science and Technology Agency, and Graduate School of Science and Engineering and Frontier Collaborative Research Center, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan. |
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| Abstract: | The triphenyl phosphite-palladium complex was found to effect catalytic substitution reactions of allylic alcohols via a direct C-O bond cleavage. The dehydrative etherification proceeded efficiently without any cocatalysts and bases to give allylic ethers in good to excellent yields. |
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