Molecular structure of (3,5-diallylisocyanuratomethyl)bis(chloromethyl)phosphine oxide. Synthesis of (3,5-diallylisocyanuratomethyl)phosphine sulfides |
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| Authors: | A S Balueva A S Dokuchaev S R Prokhorova A P Filippova G N Nikonov |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kasan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation |
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| Abstract: | X-Ray study of the (3,5-diallylisocyanuratomethyl)bis(chloromethyl)phosphine oxide showed that the phosphorylmethyl group is bonded to the nitrogen atom of the cycle. Reaction of the tris(chloromethyl)phosphine sulfide with sodium diallylisocyanurate gave (3,5-diallylisocyanuratomethyl)bis(chloromethyl)phosphine sulfide, and treatment of the tris(3,5-diallylisocyanuratomethyl)phosphine oxide with phosphorus pentasulfide gave a tris(3,5-diallylisocyanuratomethyl)bis(chloromethyl)phosphine sulfide.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1446–1448, August, 1993. |
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| Keywords: | (3 5-diallylisocyanuratomethyl)bis(chloromethyl)phosphine oxide molecular structure (3 5-diallylisocyanuratomethyl)bis(chloromethyl)phosphine sulfide tris(3 5-diallyl-isocyanuratomethyl)bis(chloromethyl)phosphine sulfide synthesis |
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