Electrochemical synthesis of carbonyl- and phosphoryl-containing methano[60]fullerenes |
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| Authors: | V V Yanilkin V P Gubskaya N V Nastapova L Sh Berezhnaya I E Ismaev Yu Ya Efremov I A Nuretdinov |
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| Institution: | (1) Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation |
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| Abstract: | The combined electrochemical reduction of fullerene C60 in the presence of p-bromo-benzoyldibromomethane or bis(diisopropoxyphosphoryl)dibromomethane at a brass electrode in a mixed solvent o-dichlorobenzene-MeCN (3:1 v/v)/0.05 M Bu4NBF4 at room temperature affords 61-(p-bromobenzoyl)methano60]fullerene or 61,61-bis(diisopropoxyphosphoryl)methano60]fullerene, respectively, in  50% yields.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2681–2685, December, 2004. |
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| Keywords: | electroreduction synthesis fullerene methanofullerene |
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