Synthesis of organic phosphines and phosphine oxides from elemental phosphorus and phosphine in the presence of strong bases |
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| Authors: | N K Gusarova S F Malysheva S N Arbuzova B A Trofimov |
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| Institution: | (1) Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, I ul. Favorskogo, 664033 Irkutsk, Russian Federation |
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| Abstract: | Data on the reactions of elemental phosphorus and phosphine with electrophilic reagents are described systematically and analyzed.
These reactions occur in the presence of strong bases and yield primary, secondary, and tertiary phosphines and phosphine
oxides.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1695–1702, September, 1998. |
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| Keywords: | elemental phosphorus phosphine reactions with electrophilic reagents superbasic systems phosphorus-centered nucleophiles organic phosphines phosphine oxides |
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