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Catalytic properties of spinel-type complex oxides in oxidation reactions
Authors:G N Pirogova  N M Panich  R I Korosteleva  Yu V Tyurkin  Yu V Voronin
Institution:(1) Institute of Phisical Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117915 Moscow, Russian Federation
Abstract:The catalytic activity of MIMII 2O3 spinel-type complex oxides (MI = Cu, Ni, Mn, Zn, Mg, Co, MII = Co, Cr, Al) in the oxidation of CO and ethylbenzene has been investigated. The Co-containing catalysts were more active than the Cr- and Al-containing catalysts. The nature of the cation influenced the catalytic activity. Higher activities were observed for the catalysts containing two transition elements. A correlation between the catalytic and adsorption properties was established.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1730–1732, October, 1994.
Keywords:catalytic oxidation  spinels  carbon monoxide  ethylbenzene  chemisorption
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