Acyl iodides in organic and organoelement chemistry |
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| Authors: | M G Voronkov N N Vlasova A V Vlasov |
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| Institution: | 1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation
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| Abstract: | This review is focused on our and literature data on reactions of acyl iodides RC(O)I with organic (alcohols, ethers, esters, carboxylic acids, amino acids, tertiary amines, nitrogen heterocycles, carbamides, thiocarbamides, and thiols) and organoelement compounds (alkoxy silanes, siloxanes, silylamines, silazanes, silicon-containing amines, and ethynyl silanes, germanes, and stannanes). Photolysis of acyl iodides in arene medium yields a-diketones, products of photochemical Friedel-Crafts acylation and iodination of arenes, and polyarylenation. |
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