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Adsorption of perfluoropropane on the PAC microporous carbon adsorbent
Authors:Fomkin  A A  Nikiforov  Yu V  Sinitsyn  V A  Savel"ev  E G
Institution:(1) Russian Academy of Sciences, Institute of Physical Chemistry, 31 Leninsky prosp., 119991 Moscow, Russian Federation;(2) Closed-end Company ldquoOstrov,rdquo, 5 ul. Kommunisticheskaya, 460012 Mytishchi, Moscow Region, Russian Federation
Abstract:The adsorption of perfluoropropane (N3F8) on the PAC microporous carbon adsorbent, which is close in properties to monoporous adsorbents, was studied at temperatures of 216, 243, 295, 318, and 343 K in the pressure interval from 1 to 1·105 Pa. The adsorption isosters are well approximated by straight lines in the studied interval of temperatures and pressures. The dependence of the isosteric heats of adsorption on filling is described by a curve with a maximum in the region of high fillings. Such a curve is characteristic of adsorbents with a narrow pore size distribution.
Keywords:adsorption  perfluoropropane  carbon adsorbent  isosters  heats of adsorption  porous structures
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