Complexes of rhodium carbonylchloride and phosphorus(iii) cyanides in mediated electrochemical reduction of 2-carbomethoxy-2-methyl-1,1-dichlorocyclopropane期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Complexes of rhodium carbonylchloride and phosphorus(iii) cyanides in mediated electrochemical reduction of 2-carbomethoxy-2-methyl-1,1-dichlorocyclopropane

Authors:	V V Yanilkin N I Maksimyuk V N Nazmutdinova L P Chirkova

Institution:	(1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan, Russian Federation

Abstract:	Electrochemical reduction of the complexes Rh(CO)ClL₂ L = (EtO)₂PCN (1), Ph₂PCN (2)] and Rh₂(CO)₄L L = P(CN)₃ (3), $Ph\begin{array}{{20}c} P \\ \| \\ {CN} \\ \end{array} ---\begin{array}{{20}c} P \\ \| \\ {CN} \\ \end{array} Ph$ (4)] and their catalytic properties in electrochemical reduction of 2-carbomethoxy-2-methyl-1,1-dichloro-cyclopropane were studied. The catalytic electroreduction of a substrate at the reduction potentials of the central ion was developed for complexes2–4. This process is accelerated substantially for complexes2 and3 in the presence of anthracene.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1970–1972, October, 1995.

Keywords:	electrochemistry metal complexes dichlorocyclopropane kinetics reduction
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