| Synthesis and Crystal Structure of （Et4N）3[{V（o—C6H4OS）3}2Na] |
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| 引用本文： | 温庭斌,徐勇进,等.Synthesis and Crystal Structure of （Et4N）3[{V（o—C6H4OS）3}2Na][J].结构化学,1995,14(2):151-156. |
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| 作者姓名： | 温庭斌 徐勇进 等 |
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| 作者单位： | State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 3500 |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ（Ｅｔ_４Ｎ）_３［｛Ｖ（ｏ－Ｃ_６Ｈ_４ＯＳ）_３｝_２Ｎａ］￥ＷｅｎＴｉｎｇ－Ｂｉｎ；ＸｕＹｏｎｇ－Ｊｉｎ；ＳｈｉＪｉ－Ｃｈｅｎｇ；ＤｅｎｇＹｕ－Ｈｅｎｇ；ＣｈｅｎＣｈａｎｇ－Ｎｅｎｇ；Ｌｉｕ...
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| 关 键 词： | 合成 晶体结构 金属配合物 钒 四乙基氮配位体 O－巯苯醇配位体 |
Synthesis and Crystal Structure of(Et_4N)_3[{V(o-C_6H_4OS)_3}_2Na] |
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| Wen Ting-Bin, Xu Yong-Jin, Shi Ji-Cheng, Deng Yu-Heng,Chen Chang-Neng, Liu Qiu-Tian, Kang Bei-Sheng,.Synthesis and Crystal Structure of(Et_4N)_3[{V(o-C_6H_4OS)_3}_2Na][J].Chinese Journal of Structural Chemistry,1995,14(2):151-156. |
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| Authors: | Wen Ting-Bin Xu Yong-Jin Shi Ji-Cheng Deng Yu-Heng Chen Chang-Neng Liu Qiu-Tian Kang Bei-Sheng |
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| Institution: | [1]StateKeyLaboratoryofStructuralChemistryandFujianIn [2]StateKeyLaboratoryofStructura |
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| Abstract: | Et_4N)_3 V(mp)_3Na(mp)_3V] was obtained from the reaction of (NH_4)_3VS_4, FeCl_2, Na_2mp(H_2mp=o-mercaptophenol,o-HSC_6H_4OH) and Et_4NCl in CH_3CN. C_(60)H_(84)N_3NaO_6S_6V_2, M_r=1260. 61, monoclinic, space group C2/c with a=24. 825(8) . b=14.716(5) , c=18. 419(10)A,β=94. 57(3)°, V=6707. 54 A￣3;Z=4, Dc=1. 248 g/cm￣3. μ= 5. 002 cm￣(-1). F(000)=2664. The structure was solved by direct methods and refined to final R(Rω)=0.059(0.059) for 3183 observed reflections with I≥2.5σ(I). The centrosymmetric anion of the title compound contains two V(mp)_3]￣(2-) fragments linked by a sodium ion, the crystallographic center of symmetry , through the μ2-O bridges. The Ⅴ(Ⅳ) atom is in a coordination environment intermediate between a trigonal prism and an ideal octahedron. |
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| Keywords: | synthesis crystal structure o-mercaptophenol vanadium complex |
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