| Structural Characterization of Chiral Sulfido Cluster(η~5-C_5H_5) WFeCo(CO)_8 (μ_3-S) |
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| 作者姓名： | XU Feng SUN Wen-Hua YANG Shi-Yan YIN Yuan-Qi |
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| 作者单位： | XU Feng; SUN Wen-Hua; YANG Shi-Yan; YIN Yuan-Qi (State Key Laboratory for OXO Synthesis and Selected Oxidation Annzhou Institute of Chemical Physics，the Chinese Academy of Sciences，Lanzhou 730000 |
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| 摘 要： | 1INtrODUCTIONThethiophilicpropertyoftransitionmetalshasbeensuccessfullyusedforthesynthesisofsulfidoclusterli.ComPOundscontainingsulfidoligandsareimportantinvariousareasofmodernchemistry"--".WehaverePOrtedthesynthesesandstructuresofaserialmixedsulfidoclustersts'6i.Theelectrophilic--additionsubstituenteliminationreactionmechanismwasalsoproPOsed.Asapartofcontinuouswork,herewereportthesynthesisandcharacterizationofthetitlecluster.2EXPERIMENTALAlloperationswerecarriedoutunderhighlypure…
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Structural Characterization of Chiral Sulfido Cluster (η~5-C_5H_5) WFeCo (CO)_8 (μ_3-S) |
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| XU Feng, SUN Wen-Hua, YANG Shi-Yan, YIN Yuan-Qi.Structural Characterization of Chiral Sulfido Cluster (η~5-C_5H_5) WFeCo (CO)_8 (μ_3-S)[J].Chinese Journal of Structural Chemistry,1997(1). |
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| Authors: | XU Feng SUN Wen-Hua YANG Shi-Yan YIN Yuan-Qi |
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| Abstract: | The chiral sulfido cluster (η5-C5H5)WFeCo(CO)8(μ3--S) was synthesized by refluxing a solution of HFe2Co(CO)9 (μ3,--S) and (η5-C5H5)Fe(CO)3Cl in tetrahydrofuran. It was characterized by elemental analysis, IR and 1H/13C--NMR. Theproposal concerning mechanism was discussed herewith and the structure was reportedas well. Crystallographic data: Mr= 563. 85, monoclinicl P21/n(# 14); a= 8. 009(2), b= 17. 600(5), c=12. 003(4) A; β=95. 91(2)°; V= 1683. 0 (9) A3; Z=4;Dc=2. 22 g. cm-3; F(000) = 1048, μ=89. 27 cm-1 ; final R=0. 039 and Rw=0. 049for 2121 observable reflections with (I≥3. cσ(I) ). The crystal structure determinationshows that S atom coordinates to all three metal (W,Fe,Co) atoms in a μ3,-fashion,thetitle cluster core has the tetrahedral skeleton. |
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| Keywords: | heterometallic cluster carbonyl sulfido tetrahedral framework |
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