| A New 1D Zinc Coordination Polymer Constructed by 1-Naphthylacetate and 4,4＇-bpy：Synthesis,Structure and Luminescent Property |
| |
| 作者姓名： | ZHOU Jian-Min NIU Xian-Chun |
| |
| 作者单位： | [1]College of Chemistry and Life Science,Guangdong University of Petrochemical Technology,Maoming 525000,China [2]College of Chemical and Environmental Engineering,Guangdong University of Petrochemical Technology,Maoming,Guangdong 525000,China |
| |
| 基金项目： | supported by the Guangdong University of Petrochemical Technology |
| |
| 摘 要： | One new zinc coordination polymer,Zn(NAA)2(4,4'-bpy)]n(1,HNAA = 1-naphthaleneacetic acid,4,4'-bpy = 4,4'-bipyridine),has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectroscopy,thermogravimetric analysis(TGA),and single-crystal X-ray diffraction.Coordination polymer 1 is of monoclinic system,space group Cc with a = 9.8720(6),b = 16.7397(9),c = 17.0371(12) ,β = 104.8080(10)°,V = 2721.9(3)3,C34H26N2O4Zn,Z = 4,Mr = 591.94,Dc = 1.444 g/cm3,μ(MoKα) = 0.946 mm-1,F(000) = 1224,the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I > 2σ(I).1 exhibits an interesting one-dimensional chain structure.Furthermore,the luminescent property of 1 has also been investigated.
|
| 关 键 词： | zinc coordination polymer crystal structure luminescent |
A New 1D Zinc Coordination Polymer Constructed by 1-Naphthylacetate and 4,4＇-bpy：Synthesis,Structure and Luminescent Property |
| |
| ZHOU Jian-Min,NIU Xian-Chun.A New 1D Zinc Coordination Polymer Constructed by 1-Naphthylacetate and 4,4＇-bpy：Synthesis,Structure and Luminescent Property[J].Chinese Journal of Structural Chemistry,2012,31(3):361-366. |
| |
| Authors: | ZHOU Jian-Mina NIU Xian-Chun |
| |
| Institution: | 1. College of Chemistry and Life Science,Guangdong University of Petrochemical Technology,Maoming 525000,China
2. College of Chemical and Environmental Engineering,Guangdong University of Petrochemical Technology,Maoming,Guangdong 525000,China |
| |
| Abstract: | One new zinc coordination polymer,Zn(NAA)2(4,4’-bpy)]n(1,HNAA = 1-naphthaleneacetic acid,4,4’-bpy = 4,4’-bipyridine),has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR spectroscopy,thermogravimetric analysis(TGA),and single-crystal X-ray diffraction.Coordination polymer 1 is of monoclinic system,space group Cc with a = 9.8720(6),b = 16.7397(9),c = 17.0371(12) ,β = 104.8080(10)°,V = 2721.9(3)3,C34H26N2O4Zn,Z = 4,Mr = 591.94,Dc = 1.444 g/cm3,μ(MoKα) = 0.946 mm-1,F(000) = 1224,the final R = 0.0282 and wR = 0.0720 for 3300 observed reflections with I > 2σ(I).1 exhibits an interesting one-dimensional chain structure.Furthermore,the luminescent property of 1 has also been investigated. |
| |
| Keywords: | zinc coordination polymer crystal structure luminescent |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
