| Synthesis and Structural Characterization of 2,3-Bis（hydroxymethyl）-2,3-dinitro-1,4-butanediol |
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| 作者姓名： | BI Fu-Qiang WANG Bo-Zhou FAN Xue-Zhong XU Cheng GE Zhong-Xue LIU Qing ZHANG Guo-Fang |
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| 作者单位： | [1]Xi＇an Modern Chemistry Research Institute,Xi＇an 710065,China [2]Key Laboratory of Applied Surface and Colloid Chemistry,Ministry of Education/School of Chemistry ＆ Chemical Engineering,Shaanxi Normal University,Xi＇an 710062,China |
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| 基金项目： | the National ＂973＂ project |
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| 摘 要： | 2,3-Bis(hydroxymethyl)-2,3-dinitro-1,4-butanediol(C6H12N2O8) was synthesized by condensation,cyclization,oxidative dimerization and deketalization of nitromethane with a total yield of 42.4%.The structure of the title compound was characterized by 1H NMR,13C NMR,FT-IR,elementary analysis,and X-ray single-crystal diffraction analysis,which reveals that the title compound crystallizes in triclinic,space group P with a = 0.6324(2),b = 0.6454(3),c = 0.7062(3) nm,α= 111.550(4),β= 95.505(4),γ= 113.395(4)°,V = 0.23595(16) nm3,Z = 1,Mr = 240.18,Dc = 1.690 g·cm-3,μ = 0.159 mm-1,F(000) = 126,R = 0.0304 and wR = 0.0907.
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| 关 键 词： | 2 3-bis(hydroxymethyl)-2 3-dinitro-1 4-butanediol synthesis characterization crystal structure |
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