| Crystal Structure and Electrochemical Behavior of Copper Complex with 6-Hydroxymethyl-substituted Tris（2-pyridylmethyl） Amine, [CuCl（C19H20N4O）]ClO4 |
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| 引用本文： | 高云玲,彭孝军,孙世国,孙立成,陈昌能,刘秋田,黄德光.Crystal Structure and Electrochemical Behavior of Copper Complex with 6-Hydroxymethyl-substituted Tris（2-pyridylmethyl） Amine, [CuCl（C19H20N4O）]ClO4[J].结构化学,2004,23(11):1262-1265. |
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| 作者姓名： | 高云玲 彭孝军 孙世国 孙立成 陈昌能 刘秋田 黄德光 |
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| 作者单位： | GAO Yun-Linga PENG Xiao-Juna② SUN Shi-Guoa SUN Li-Chenga CHEN Chang-Nengb LIU Qiu-Tianb HUANG De-Guangb a(State Key Laboratory of Fine Chemicals，Dalian University of Technology，Dalian 116012，China) b(State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China) |
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| 基金项目： | This project was supported by “973” program of the Ministry of Science and Technology of
China and National Natural Science Foundation of China (20376010，20128005) |
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| 摘 要： | 1 INTRODUCTION The copper plays an important role in metallo-proteins involved in significant electron transfer andoxygenation reactions1]. Various model complexesfor such enzymes have been synthesized and the re-activity to oxygen been investigated…
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| 关 键 词： | 合成 晶体结构 电化学行为 铜配合物 6-羟甲基-取代三（2-吡啶甲基）胺 循环伏安法 |
Crystal Structure and Electrochemical Behavior of Copper Complex with 6-Hydroxymethyl-substituted Tris(2-pyridylmethyl) Amine,[CuCl(C19H20N4O)]ClO4 |
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| Abstract: | A Cu(II) complex CuCl(C19H20N4O)]ClO4 1 containing hydroxymethyl substituted TPA (TPA = tris(2-pyridylmethyl)amine) was prepared. It crystallizes in monoclinic, space group P21/c with a = 11.7628(2), b = 13.0083(3), c = 15.11280(10)A, β = 108.724(2)°, V = 2190.09(7)A3, Mr = 518.83, Z = 4, T = 293(2) K, Dc = 1.574 g/cm3, μ = 1.280 mm-1, F(000) = 1060 and S = 1.085. The final R = 0.0543 and wR = 0.1433 for 2693 observed reflections with I >2σ(I). The pentacoordinated copper (II) complex assumes an approximate square pyramidal geometry. Cyclic voltammetry measurement of the complex showed a quasi-reversible CuII/CuI redox couple with E1/2 = -0.467 v and ΔE = 68 mv. |
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| Keywords: | copper complex substituted TPA cyclic voltammetry |
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