| Self-assembly and Crystal Structure of a Novel Inorganic-organic Hybrid Coordination： {（C12H14N2）[Ag2I4]}n |
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| 引用本文： | 李浩宏,陈之荣,黄长沧,任永刚,陈其辉.Self-assembly and Crystal Structure of a Novel Inorganic-organic Hybrid Coordination： {（C12H14N2）[Ag2I4]}n[J].结构化学,2004,23(3):288-291. |
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| 作者姓名： | 李浩宏 陈之荣 黄长沧 任永刚 陈其辉 |
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| 作者单位： | Department of Chemistry，Fuzhou University，Fuzhou，Fujian 350002，China |
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| 基金项目： | This work was supported by the Foundation of Education Committee of Fujian province (JB01020) |
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| 摘 要： | 1 INTRODUCTION The construction of low-dimensional organic- inorganic hybrid material with novel properties re- presents new directions in solid-state chemistry1, 2]. Generally the physical properties of such low di- mensional compounds differ from tho…
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| 关 键 词： | 晶体结构 有机-无机复合物 {（C12H14N2）[Ag2I4]}n 水热合成 碘化银 四铵 EDP |
Self-assembly and Crystal Structure of a Novel Inorganic-organic Hybrid Coordination:{(C12H14N2)[Ag2I4]}n |
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| LI Hao-hong,CHEN Zhi-rong,HUANG Chang-cang,REN Yong-Gang,CHEN Qi-hui.Self-assembly and Crystal Structure of a Novel Inorganic-organic Hybrid Coordination:{(C12H14N2)[Ag2I4]}n[J].Chinese Journal of Structural Chemistry,2004,23(3):288-291. |
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| Authors: | LI Hao-hong CHEN Zhi-rong HUANG Chang-cang REN Yong-Gang CHEN Qi-hui |
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| Abstract: | A novel coordination polymer {(C12H14N2)Ag2I4]}n (C12H14N2]2 = N,N-1,2- ethyl-dipyridinium (EDP)) was synthesized by the reaction of AgI with EDP (pH = 6.5) at room temperature and structurally characterized by X-ray single-crystal diffraction analysis. The title compound crystallizes in monoclinic, space group P21/n with a = 7.278(2), b = 23.658(2), c = 12.038(2) , b = 98.25, V = 2051.3(7) 3, Z = 4, Dc = 2.945 g/cm3, F(000) = 1624, C12H14Ag2I4N2, Mr = 909.59, m(MoKa) = 7.922 mm-1, the final R = 0.0321 and wR = 0.0615 for 3079 observed reflections with I > 2s(I). The title compound consists of cations (C12H14N2]2 ) and anion chain (Ag2I42-) which are combined by static attracting forces in the crystal. |
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| Keywords: | coordination polymers template synthesis iodide quaternary ammonium |
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