| Synthesis,Crystal Structure and Electrochemical Property of the Ferrocenyl Schiff-base (E)-N’(Ferrocene Ethylidene)Picolino Hydrazide |
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| 引用本文： | 李传碧,孙丽娟,张首才,张爱萍,富超,王家军.Synthesis,Crystal Structure and Electrochemical Property of the Ferrocenyl Schiff-base (E)-N’(Ferrocene Ethylidene)Picolino Hydrazide[J].结构化学,2011,30(3):308-311. |
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| 作者姓名： | 李传碧 孙丽娟 张首才 张爱萍 富超 王家军 |
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| 作者单位： | LI Chuan-Bi,ZHANG Shou-Cai,ZHANG Ai-Ping,FU Chao,WANG Jia-Jun(Chemistry College of Jilin Normal University, Siping, Jilin 136000, China);SUN Li-Juan(Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping, Jilin 136000, China) |
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| 基金项目： | supported by the Chemistry College of Jilin Normal University |
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| 摘 要： | A novel Schiff-base compound based on ferrocene C18H17OFeN3 (1) has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic, space group P21/c with a = 19.2343(17), b = 10.5084(9), c = 7.9373(7) , β = 97.7740°, Z = 4, V = 1589.6(2) 3, Dc = 1.451 g/cm3, μ(MoKα) = 0.956 mm-1, F(000) = 720, the final R = 0.0343 and wR = 0.0973 for 2759 observed reflections (I > 2σ(I)). Electrochemical measurements exhibit that compound 1 undergoes a reversible one-electron redox process.
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| 关 键 词： | Schiff碱 电化学测量 晶体结构 二茂铁 合成 标题化合物 物业 酰肼 |
Synthesis,Crystal Structure and Electrochemical Property of the Ferrocenyl Schiff-base (E)-N'(Ferrocene Ethylidene)Picolino Hydrazide |
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| LI Chuan-Bi,SUN Li-Juan,ZHANG Shou-Cai,ZHANG Ai-Ping,FU Chao,WANG Jia-Jun.Synthesis,Crystal Structure and Electrochemical Property of the Ferrocenyl Schiff-base (E)-N'(Ferrocene Ethylidene)Picolino Hydrazide[J].Chinese Journal of Structural Chemistry,2011,30(3):308-311. |
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| Authors: | LI Chuan-Bi SUN Li-Juan ZHANG Shou-Cai ZHANG Ai-Ping FU Chao WANG Jia-Jun |
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| Abstract: | A novel Schiff-base compound based on ferrocene C18H17OFeN3 (1)has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic,space group P21/c with a = 19.2343(17), b = 10.5084(9), c = 7.9373(7) (A), β = 97.7740°, Z = 4, V=1589.6(2) (A)3, Dc= 1.451 g/cm3, μ(MoKα) = 0.956 mm-1, F(000) = 720, the final R = 0.0343 and wR =0.0973 for 2759 observed reflections (I > 2σ(I)). Electrochemical measurements exhibit that compound 1 undergoes a reversible one-electron redox process. , V= |
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| Keywords: | crystal structure electrochemical property Schiff-base acetylferrocene |
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