| Synthesis and Characterization of [NH3（CH2）2NH2（CH2）2NH3]BiCl6 |
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| 引用本文： | 徐刚,付明来,蔡丽珍,张章静,郭国聪,黄锦顺.Synthesis and Characterization of [NH3（CH2）2NH2（CH2）2NH3]BiCl6[J].结构化学,2006,25(3):338-342. |
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| 作者姓名： | 徐刚 付明来 蔡丽珍 张章静 郭国聪 黄锦顺 |
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| 作者单位： | State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences，Fuzhou Fujian 350002 China Graduate School Chinese Academy of Sciences Beijing 100039 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China Graduate School Chinese Academy of Sciences Beijing 100039 China，Fuzhou Fujian 350002 China，Fuzhou Fujian 350002 China |
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| 基金项目： | We gratefully acknowledge the financial support of the NNSF of China (20131020) and NSF of Fujian Province (2003I031) |
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| 摘 要： | 1 INTRODUCTION During the past decade, a series of organic-inor- ganic hybrid compounds based on metal halide units have been prepared and studied1]. The combination of organic and inorganic components at the mole- cular level affords us the opportunity to design new hybrid materials and modulate the properties of components2]. As a result, some interesting proper- ties, such as non-linear optical3], interesting magne- tic4], efficient luminescence2], ideal thermal and mechanical sta…
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| 关 键 词： | 合成 表征 [NH3（CH2）2NH2（CH2）2NH3]BiCl6 铋酸盐 卤化物 无机-有机混合物 结构分析 |
Synthesis and Characterization of [NH3(CH2)2NH2(CH2)2NH3]BiCl6 |
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| XU Gang,FU Ming-Lai,CAI Li-Zhen,ZHANG Zhang-Jing,GUO Guo-Cong,HUANG Jin-Shun.Synthesis and Characterization of [NH3(CH2)2NH2(CH2)2NH3]BiCl6[J].Chinese Journal of Structural Chemistry,2006,25(3):338-342. |
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| Authors: | XU Gang FU Ming-Lai CAI Li-Zhen ZHANG Zhang-Jing GUO Guo-Cong HUANG Jin-Shun |
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| Institution: | 1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;Graduate School, Chinese Academy of Sciences, Beijing 100039, China
2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
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| Abstract: | The title compound (NH3(CH2)2NH2(CH2)2NH3]BiCl6, Mr = 527.88 ) has been syn- thesized by diffusion method and its crystal structure was determined by X-ray diffraction method. It crystallizes in orthorhombic, space group P212121 with a = 6.8444(4), b = 13.6329(10), c = 15.6641(12)(A), V = 1461.60(18) (A)3, Z = 4, Dc = 2.399 g/cm3, F(000) = 984, μ(MoKα) = 13.132 mm-1 and T = 293(2) K. The final R = 0.0294 and wR = 0.0490 for 2325 observed reflections with I > 2б(I). Each bismuth atom in the present compound is coordinated by six chlorine atoms to furnish a slightly distorted octahedral geometry. It is worthy to note that each adjacent BiCl6]3- and H3dien]3+ entities are linked by hydrogen bonds to form two right- and left-handed helical double-chains running along the b axis. These two helical double-chains are interlaced into quadruple-stranded braid to give rise to a three- dimensional network. The optical absorption spectrum of the compound reveals the appearance of a sharp optical gap of 3.30 eV. |
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| Keywords: | bismuthate halide hybrid inorganic-organic |
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